Methods for automating and improving the robustness of linear Kramers–Kronig tests for the purposes of validating immittance spectra

Methods for automating the selection of key parameters for linear Kramers–Kronig tests are described. These methods include not only new methods and improvements to existing methods for suggesting the optimum number of time constants, but also methods for estimating the limits of the solution space. Methods for optimizing the range of time constants and a method for suggesting the representation of the immittance spectrum are also described. These methods are evaluated using both valid and invalid synthetic immittance spectra that present various challenges. Practical considerations regarding the implementation of the linear Kramers–Kronig tests and the various methods, the choice of linear Kramers–Kronig test and data representation to use, and the visualization and interpretation of results are also discussed.

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Publication Details

Journal
Electrochimica Acta
Published
2024-08-23
DOI
https://doi.org/10.1016/j.electacta.2024.144951
Citations
6
Primary Topic
Calibration and Measurement Techniques
Type
article
Field-Weighted Citation Impact
7.79

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article

Methods for automating and improving the robustness of linear Kramers–Kronig tests for the purposes of validating immittance spectra

Johan Bobacka, Ville Yrjänä
6 citations
Electrochimica Acta
Calibration and Measurement Techniques
7.79
article

Methods for automating and improving the robustness of linear Kramers–Kronig tests for the purposes of validating immittance spectra

Johan Bobacka, Ville Yrjänä
article en
6 citations

Abstract

Methods for automating the selection of key parameters for linear Kramers–Kronig tests are described. These methods include not only new methods and improvements to existing methods for suggesting the optimum number of time constants, but also methods for estimating the limits of the solution space. Methods for optimizing the range of time constants and a method for suggesting the representation of the immittance spectrum are also described. These methods are evaluated using both valid and invalid synthetic immittance spectra that present various challenges. Practical considerations regarding the implementation of the linear Kramers–Kronig tests and the various methods, the choice of linear Kramers–Kronig test and data representation to use, and the visualization and interpretation of results are also discussed.

Electrochimica ActaVol. 504
Åbo Akademi University (FI)
Suomen Kulttuurirahasto, Varsinais-Suomen Rahasto
Openalex Percentile: Top 3%
Calibration and Measurement Techniques
7.79
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Methods for automating and improving the robustness of linear Kramers–Kronig tests for the purposes of validating immittance spectra — Johan Bobacka, Ville Yrjänä · Electrochimica Acta (2024) | TGRS Research Map | TGRS