Dual Cocatalysts on Covalent Organic Framework as Charge Transfer Mediator Facilitating Photocatalytic Water Oxidation

Abstract Covalent organic frameworks (COFs) have been regarded as promising photocatalytic materials. However, the sluggish diffusion of photoinduced charges in a single‐component COF remains the obstacles that have to be overcome. Here, we demonstrate a synthesis of a COF bearing dual cocatalysts Co 3 O 4 and Re complex as photocatalyst for water oxidation. The dual cocatalysts are coordinated on the COF, and enable the spatial separation of photoinduced charges. The generated electrons were attracted to Re moiety, while the holes were localized on Co 3 O 4 cocatalyst for water oxidation to produce O 2 product. The synergy of dual cocatalysts of COF promote the charge separation and redox reaction. Moreover, hydroxyl radicals generated from the hydration of COF contribute to O−O bond formation, which is the key step of O 2 formation. Accordingly, an excellent O 2 production rate of 400 μmol g −1 h −1 under visible light irradiation was obtained. This work may pave the way to the development of highly efficient COF photocatalysts for solar energy conversion.