Rapid Prediction of the Lithium Content in Plants by Combining Fractional-Order Derivative Spectroscopy and Wavelet Transform Analysis

Quickly determining the metal content in plants and subsequently identifying geochemical anomalies can provide clues and guidance for predicting the location and scale of concealed ore bodies in vegetation-covered areas. Although visible, near-infrared and shortwave infrared (VNIR–SWIR) reflectance spectroscopy at wavelengths ranging from 400 to 2500 nm has been proven by many researchers to be a fast, accurate and nondestructive approach for estimating the contents of copper (Cu), lead (Pb), zinc (Zn) and other metal elements in plants, relatively few studies have been conducted on the estimation of lithium (Li) in plants. Therefore, the potential of applying VNIR–SWIR spectroscopy techniques for estimating the Li content in plants was explored in this study. The Jingerquan Li mining area in Hami, Xinjiang, China, was chosen. Three sampling lines were established near a pegmatite deposit and in a background region, canopy reflectance spectra were obtained for desert plants and Li contents were determined in the laboratory; then, quantitative relationships were established between nine different transformed spectra (including both integer and fractional orders) and the Li content was estimated using partial least squares regression (PLSR). The results showed that models constructed using high-order derivative spectra (with an order greater than or equal to 1) significantly outperformed those based on original and low-order derivative spectra (with an order less than 1). Notably, the model based on a 1.1-order derivative spectrum displayed the best performance. Furthermore, the performance of the model based on the two-layer wavelet coefficients of the 1.1-order derivative spectrum was further improved compared with that of the model based on only the 1.1-order derivative spectrum. The coefficient of determination (Rpre2) and the ratio of performance to deviation (RPD) for the validation set increased from 0.6977 and 1.7656 to 0.7044 and 1.8446, respectively, and the root mean square error (RMSEpre) decreased from 2.5735 to 2.4633 mg/kg. These results indicate that quickly and accurately estimating the Li content in plants via the proposed spectroscopic analysis technique is feasible and effective; however, appropriate spectral preprocessing methods should be selected before hyperspectral estimation models are constructed. Overall, the developed hybrid spectral transformation approach, which combines wavelet coefficients and derivative spectra, displayed excellent application potential for estimating the Li content in plants.