Heterochiral π‐Stacking Dimerization of Helical Secondary Structures with Emerging Supramolecular Chirality
A specific interface mode type was observed between helical secondary structures, in which a left-handed (M) helix binds specifically to a right-handed (P) helix along the helical axis, leading to the formation of discrete heterochiral helical dimers. Moreover, a concealed supramolecular chirality within the meso-supramolecular dimers was unexpectedly discovered by chiral induction, and was further underpinned by covalent meso-helix structures.
Authors
- Yunpeng Ge
- Hua Jiang (ORCID: https://orcid.org/0000-0002-9917-2683)
- Zeyuan Dong (ORCID: https://orcid.org/0000-0001-6509-9724)
- Wencan Li (ORCID: https://orcid.org/0000-0003-1801-071X)
- Zhenzhu Wang (ORCID: https://orcid.org/0000-0002-3648-6124)
- Zhaocheng Xu
- Yiqi Shao
Institutions
- Jilin University (CN)
- Beijing Normal University (CN)
- State Key Laboratory of Supramolecular Structure and Materials
Publication Details
- Journal
- Angewandte Chemie International Edition
- Published
- 2024-08-22
- DOI
- https://doi.org/10.1002/anie.202414317
- Citations
- 5
- Primary Topic
- Synthesis and Properties of Aromatic Compounds
- Type
- article
- Field-Weighted Citation Impact
- 1.25
Funders
- National Natural Science Foundation of China