Volumetric Flask with White and Blue Balls: Demonstration of Microcanonical Ensemble of Small Populations

The microstates of an isolated system indicate the different distributions of the energy of a system over the set of particles of the system. Microstates with the same (quantum states) occupation number form a configuration set. All microstates have the same probability of occurrence. Students determined the probability distribution of the configurations in a model experiment demonstrating the ergodic theory. The model experiment required a volumetric flask with white and blue plastic balls. The sequential order (repeated permutation) of the plastic balls in the neck of the flask corresponds to a microstate. The experiment was performed after the theoretical lecture.

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Publication Details

Journal
Journal of Chemical Education
Published
2024-08-21
DOI
https://doi.org/10.1021/acs.jchemed.4c00496
Primary Topic
Experimental and Theoretical Physics Studies
Type
article
Field-Weighted Citation Impact
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article

Volumetric Flask with White and Blue Balls: Demonstration of Microcanonical Ensemble of Small Populations

Mihalj Poša
Journal of Chemical Education
Experimental and Theoretical Physics Studies
article

Volumetric Flask with White and Blue Balls: Demonstration of Microcanonical Ensemble of Small Populations

Mihalj Poša
article en

Abstract

The microstates of an isolated system indicate the different distributions of the energy of a system over the set of particles of the system. Microstates with the same (quantum states) occupation number form a configuration set. All microstates have the same probability of occurrence. Students determined the probability distribution of the configurations in a model experiment demonstrating the ergodic theory. The model experiment required a volumetric flask with white and blue plastic balls. The sequential order (repeated permutation) of the plastic balls in the neck of the flask corresponds to a microstate. The experiment was performed after the theoretical lecture.

Journal of Chemical EducationVol. 101(9)
University of Novi Sad (RS)
Openalex Percentile: Top 87%
Experimental and Theoretical Physics Studies
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