Using the pH sensitivity of switchable surfactants to understand the role of the alkyl tail conformation and hydrogen bonding at a molecular level in elucidating emulsion stability

By adjusting the pH of water, the charge of the adsorbed DPDA molecules, their self-assembly, the organization of interfacial molecules, and ultimately the stability of the emulsion were tuned. At pH 7.0, the SFG spectra of DPDA showed that the interfacial alkyl chains were relatively well-ordered, while water molecules also had stronger H-bonding interactions. As a result, the oil-water emulsion showed improved stability. When water was at a high pH, the water molecules had fewer H-bonding interactions and relatively disordered alkyl chains at the interface, providing desirable conditions for demulsification. These observations were compatible with the observation in bulk emulsion preparation, confirming that alkyl chain packing and water H-bonding interactions at the interface contribute to overall emulsion stability.