Barrier height enhancement in β-Ga2O3 Schottky diodes using an oxygen-rich ultra-thin AlOx interfacial layer

Schottky barrier height (SBH) enhancement directly translates into increased breakdown voltage (VBR) of β-Ga2O3 Schottky barrier diodes (SBDs). In this work, ultra-thin (5, 10, and 15 Å) oxygen-rich AlOx interfacial layers (ILs), deposited using plasma-enhanced atomic layer deposition, are shown to enhance the SBH of post-metallization oxygen annealed Pt/AlOx/β-Ga2O3 SBDs by up to 0.8 eV resulting in a maximum VBR of nearly 500 V (2× gain) on 2–4 × 1016 cm−3 doped substrates, without compromising the specific on-resistance. The SBH and VBR enhancement is observed on (2¯ 01) as well as (001) surfaces. X-ray photoelectron spectroscopy (XPS) analysis shows that excess oxygen interstitial concentration in 5 Å AlOx films decreases (increases) with increasing thickness (oxygen anneal), making them more stoichiometric. The decreasing (increasing) trend in SBH and VBR with increasing IL thickness (oxygen anneal) is consistent with the XPS-derived O/Al ratio of the films and the formation of an AlOx/β-Ga2O3 interfacial dipole due to a difference in oxygen areal densities. The AlOx deposition can be easily integrated with field management methods such as field plates and guard rings that can further enhance β-Ga2O3 SBD performance.