From Meteorite to Life's Building Blocks: A possible Electrochemical Pathway to Amino Acids and Peptide Bonds

Abstract This study explores the electrochemical properties of the carbonaceous Allende CV3 meteorite, focusing on its potential as a Fe‐based catalyst derived from Mackinawite iron sulfide for electrocatalytic reactions facilitating nitrogen (N 2 ) fixation into ammonia. Through comprehensive analysis, we not only monitored the evolution of key compounds such as CN ‐ , sulfur/H 2 S, H 2 and carbonyl compounds, but also identified potential reagent carriers, indicating significant implications for the Strecker synthesis of amino acids in space environments. Initial examination revealed the presence of polypeptides, notably sequences including dimer Ala‐α‐HO‐Gly, pentamer Gly 3 ‐Ala 2 , and hexamer Gly 4 ‐(HO‐Gly) 2 . These discoveries greatly enhance our understanding of astrobiological chemistry, offering valuable insights into prebiotic processes and the potential presence of life‐building blocks throughout the universe.

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Publication Details

Journal
Chemistry - A European Journal
Published
2024-08-20
DOI
https://doi.org/10.1002/chem.202401856
Citations
1
Primary Topic
Isotope Analysis in Ecology
Type
article
Field-Weighted Citation Impact
0.46

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article

From Meteorite to Life's Building Blocks: A possible Electrochemical Pathway to Amino Acids and Peptide Bonds

Farzaneh Yari, L Bustos Fernández, Günter Hesser, Wolfgang Schöfberger
1 citations
Chemistry - A European Journal
Isotope Analysis in Ecology
0.46
article

From Meteorite to Life's Building Blocks: A possible Electrochemical Pathway to Amino Acids and Peptide Bonds

Farzaneh Yari, L Bustos Fernández, Günter Hesser, Wolfgang Schöfberger
article en
1 citations

Abstract

Abstract This study explores the electrochemical properties of the carbonaceous Allende CV3 meteorite, focusing on its potential as a Fe‐based catalyst derived from Mackinawite iron sulfide for electrocatalytic reactions facilitating nitrogen (N 2 ) fixation into ammonia. Through comprehensive analysis, we not only monitored the evolution of key compounds such as CN ‐ , sulfur/H 2 S, H 2 and carbonyl compounds, but also identified potential reagent carriers, indicating significant implications for the Strecker synthesis of amino acids in space environments. Initial examination revealed the presence of polypeptides, notably sequences including dimer Ala‐α‐HO‐Gly, pentamer Gly 3 ‐Ala 2 , and hexamer Gly 4 ‐(HO‐Gly) 2 . These discoveries greatly enhance our understanding of astrobiological chemistry, offering valuable insights into prebiotic processes and the potential presence of life‐building blocks throughout the universe.

Chemistry - A European JournalVol. 30(57)
Johannes Kepler University of Linz (AT)
Klima- und Energiefonds, Austrian Science Fund
Responsible consumption and production
Openalex Percentile: Top 30%
Isotope Analysis in Ecology
0.46
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From Meteorite to Life's Building Blocks: A possible Electrochemical Pathway to Amino Acids and Peptide Bonds — Farzaneh Yari, L Bustos Fernández, et al. · Chemistry - A European Journal (2024) | TGRS Research Map | TGRS