Development of fluid pathways and associated diagenetic variations in a natural CO2 leaking fault zone.

Abstract Permeability within fault zones can vary through time due to repeated deformation events and rock–fluid interactions. Understanding the history of fault zone alteration is critical when building hydrogeologic models and evaluating the risk of mechanical rock failure during subsurface storage. Newly acquired drill core recovered within the fault damage zone and fault core of the Little Grand Wash fault (LGWF) is combined with observations from outcrop, optical petrography, computerized tomography image analysis, and ultrasonic velocity measurements to characterize the rock types and preserved structural deformation features within this fault zone. These data are used to understand the history of mechanical rock failure and mineralization associated with this fluid-charged fault system. We identify multiple structural features and use their cross-cutting relationships to understand the history of deformation and their association with changes in fault zone permeability and rock mechanical properties. At the LGWF zone, structural deformation features vary temporally and are used to recognize a decoupling between fault slip and fluid flow. The formation of most open-mode veins occurred after shear failure within the LGWF zone. Early-developed shear bands are cut by carbonate veins, that are in turn cut by shear fractures, followed by a second phase of vein formation and ultimately by folding in the fault core. This sequence of formation reflects changes in mechanical rock properties due to subsurface rock–fluid interactions and indicates that the alteration of rock matrix by secondary carbonate cement results in increased unconfined compressive strength, decreased permeability, and increased ultrasonic velocity. In this fault zone, and possibly other fault zones, the changes in rock properties associated with deformation can be detected through their geophysical response.