Crystal structure and Hirshfeld surface analysis of dichlorido[2-(3-cyclopentyl-1,2,4-triazol-5-yl-κ<i>N</i> <sup>4</sup>)pyridine-κ<i>N</i>]palladium(II) dimethylformamide monosolvate
This study presents the synthesis, characterization and Hirshfeld surface analysis of the title mononuclear complex, [PdCl<sub>2</sub>(C<sub>12</sub>H<sub>14</sub>N<sub>4</sub>)]·C<sub>3</sub>H<sub>7</sub>NO. The compound crystalizes in the <i>P</i>2<sub>1</sub>/<i>c</i> space group of the monoclinic system. The asymmetric unit contains one neutral complex Pd(H<i>L</i> <sup>c-Pe</sup>)Cl<sub>2</sub> [H<i>L</i> <sup>c-Pe</sup> is 2-(3-cyclo-pentyl-1,2,4-triazol-5-yl)pyridine] and one mol-ecule of DMF as a solvate. The Pd atom has a square-planar coordination. In the crystal, mol-ecules are linked by inter-molecular N-H⋯O and C-H⋯N hydrogen bonds, forming layers parallel to the <i>bc</i> plane. A Hirshfeld surface analysis showed that the H⋯H contacts dominate the crystal packing with a contribution of 41.4%. The contribution of the N⋯H/H⋯N and H⋯O/O⋯H inter-actions is somewhat smaller, amounting to 12.4% and 5%, respectively.
Authors
- Rostyslav D. Lampeka (ORCID: https://orcid.org/0000-0001-8326-4535)
- Viktoriya V. Dyakonenko (ORCID: https://orcid.org/0000-0003-4613-172X)
- Dmytro M. Khomenko (ORCID: https://orcid.org/0000-0001-7058-832X)
- Roman O. Doroshchuk
- Г В Иванова
Institutions
- National Academy of Sciences of Ukraine (UA)
- Taras Shevchenko National University of Kyiv (UA)
- Institute of General and Inorganic Chemistry (BG)
- State Scientific Institution “Institute for Single Crystals” of National Academy of Sciences of Ukraine (UA)
- Enamine (Ukraine) (UA)
Publication Details
- Journal
- Acta Crystallographica Section E Crystallographic Communications
- Published
- 2024-08-16
- DOI
- https://doi.org/10.1107/s2056989024007801
- Primary Topic
- Metal complexes synthesis and properties
- Type
- article
- Field-Weighted Citation Impact
- 0.00