Estimation of the Potential Antimony Resource in Southern China with the Geochemical Block Method

Antimony (Sb) is widely utilized in modern industries and classified as a critical mineral worldwide. China possesses the most abundant Sb mineral resources globally, with over 70% of proven reserves concentrated in southern China. However, due to excessive exploitation, the lifespan of Sb reserves is less than ten years. Therefore, the knowledge of Sb needs to be urgently strengthened. Here, the effectiveness of the geochemical block method to delineate the prospective areas of Sb deposits and determine the potential resource of Sb was studied, with geochemical data covering 2.3 million km2 across southern China. The statistical results showed that the median concentration of Sb in stream sediments (1.05 ppm) in southern China was 1.5 times that of whole China, indicating a significantly elevated background level of Sb in southern China. By setting the threshold value at 2.98 ppm, a total of nine distinct geochemical blocks were delineated. Remarkably, 85% and 76% of the large and medium Sb deposits were located within these geochemical blocks, respectively. Taking the block containing the Xikuangshan giant Sb deposit in Hunan Province as the model, the metallogenic coefficient of Sb is calculated to be 0.32%. The total potential Sb resources in southern China within a depth of 1000 m are estimated to be 21.939 million tons, which are primarily concentrated in the provinces of Hunan, Guangxi, Yunnan, and Guizhou. When the threshold value is set at 4.19 ppm, the predicted potential resources of Sb are 21.45 million tons in twelve blocks, which closely approximate 21.939 million tons. The estimated Sb resource in this study significantly surpasses the proven reserves. The periphery and deep areas of known Sb deposits still hold promising prospects for exploration. This study highlighted the effectiveness of employing the geochemical block method to estimate the potential resources of Sb and determined the ore-prospecting direction of Sb deposits. However, it is important to acknowledge and address the overestimation of predicted resources resulting from the high geological background.