ZCNC Beaded Heterostructure toward High-Performance Aluminum Batteries

We designed and prepared the ZnSe/CoSe<sub>2</sub>@NC/CNTs (ZCNC) cathode material for aluminum batteries (ABs). The ZCN (ZnSe/CoSe<sub>2</sub>@NC) is connected by the interwoven carbon nanotube (CNT) conductive network to form a beaded structure. CNTs and the carbon formed by carbonization of organic ligands is beneficial to improving the electrical conductivity of the material and reducing structural damage during cycling. The internal electric field generated at the interface of heterostructures can promote the transfer of electrons/ions. This special structure promotes ZCNC excellent electrochemical properties. At 100 mA/g, the specific capacity of the first discharge reaches 338 mAh/g, while the specific capacity after 500 cycles still reaches 217 mAh/g. Compared with ZCN and CN(CoSe<sub>2</sub>@NC), it demonstrates a great advantage.

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Publication Details

Journal
ACS Applied Materials & Interfaces
Published
2024-08-16
DOI
https://doi.org/10.1021/acsami.4c09943
Citations
11
Primary Topic
Advancements in Battery Materials
Type
article
Field-Weighted Citation Impact
2.30

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article

ZCNC Beaded Heterostructure toward High-Performance Aluminum Batteries

Wenbin Luo, Zisheng Chao, Jian Li, Yu Yi et al.
11 citations
ACS Applied Materials & Interfaces
Advancements in Battery Materials
2.30
article

ZCNC Beaded Heterostructure toward High-Performance Aluminum Batteries

Wenbin Luo, Zisheng Chao, Jian Li, Yu Yi, JinCheng Fan, Zhen Zhang
article en
11 citations

Abstract

We designed and prepared the ZnSe/CoSe<sub>2</sub>@NC/CNTs (ZCNC) cathode material for aluminum batteries (ABs). The ZCN (ZnSe/CoSe<sub>2</sub>@NC) is connected by the interwoven carbon nanotube (CNT) conductive network to form a beaded structure. CNTs and the carbon formed by carbonization of organic ligands is beneficial to improving the electrical conductivity of the material and reducing structural damage during cycling. The internal electric field generated at the interface of heterostructures can promote the transfer of electrons/ions. This special structure promotes ZCNC excellent electrochemical properties. At 100 mA/g, the specific capacity of the first discharge reaches 338 mAh/g, while the specific capacity after 500 cycles still reaches 217 mAh/g. Compared with ZCN and CN(CoSe<sub>2</sub>@NC), it demonstrates a great advantage.

ACS Applied Materials & InterfacesVol. 16(34)
Changsha University of Science and Technology (CN)
Education Department of Hunan Province, National Natural Science Foundation of China
Affordable and clean energy
Openalex Percentile: Top 11%
Advancements in Battery Materials
2.30
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ZCNC Beaded Heterostructure toward High-Performance Aluminum Batteries — Wenbin Luo, Zisheng Chao, et al. · ACS Applied Materials & Interfaces (2024) | TGRS Research Map | TGRS