2-(2,6-Diisopropylphenyl)-1-methylimidazo[1,5-a]quinolin-2-ium Tetrafluoroborate

A new heterocyclic compound, 2-(2,6-diisopropylphenyl)-1-methylimidazo[1,5-a]quinolin-2-ium tetrafluoroborate 1 was obtained from its precursor, N-(2,6-diisopropylphenyl)-N-(quinolin-2-ylmethyl)acetamide 2, by POCl3-mediated cyclization. For the first time, tertiary acetamide 2, the precursor of 1, was synthesized by using commercially available starting materials. The structure of 1 was unquestionably confirmed by 1H, 13C, 2D-NMR, and IR spectroscopies and mass spectrometry. Its optical properties were also studied.

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Publication Details

Journal
Molbank
Published
2024-08-15
DOI
https://doi.org/10.3390/m1868
Primary Topic
N-Heterocyclic Carbenes in Organic and Inorganic Chemistry
Type
article
Field-Weighted Citation Impact
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article

2-(2,6-Diisopropylphenyl)-1-methylimidazo[1,5-a]quinolin-2-ium Tetrafluoroborate

Iskra Z. Koleva, Lyuben Borislаvov, Vesela Lozanova, Rumen Lyapchev et al.
Molbank
N-Heterocyclic Carbenes in Organic and Inorganic Chemistry
article

2-(2,6-Diisopropylphenyl)-1-methylimidazo[1,5-a]quinolin-2-ium Tetrafluoroborate

Iskra Z. Koleva, Lyuben Borislаvov, Vesela Lozanova, Rumen Lyapchev, Maria Ivanova
article en

Abstract

A new heterocyclic compound, 2-(2,6-diisopropylphenyl)-1-methylimidazo[1,5-a]quinolin-2-ium tetrafluoroborate 1 was obtained from its precursor, N-(2,6-diisopropylphenyl)-N-(quinolin-2-ylmethyl)acetamide 2, by POCl3-mediated cyclization. For the first time, tertiary acetamide 2, the precursor of 1, was synthesized by using commercially available starting materials. The structure of 1 was unquestionably confirmed by 1H, 13C, 2D-NMR, and IR spectroscopies and mass spectrometry. Its optical properties were also studied.

MolbankVol. 2024(3)
Bulgarian Academy of Sciences (BG), Institute of General and Inorganic Chemistry (BG), Sofia University "St. Kliment Ohridski" (BG)
Openalex Percentile: Top 90%
N-Heterocyclic Carbenes in Organic and Inorganic Chemistry
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