2-(2,6-Diisopropylphenyl)-1-methylimidazo[1,5-a]quinolin-2-ium Tetrafluoroborate
A new heterocyclic compound, 2-(2,6-diisopropylphenyl)-1-methylimidazo[1,5-a]quinolin-2-ium tetrafluoroborate 1 was obtained from its precursor, N-(2,6-diisopropylphenyl)-N-(quinolin-2-ylmethyl)acetamide 2, by POCl3-mediated cyclization. For the first time, tertiary acetamide 2, the precursor of 1, was synthesized by using commercially available starting materials. The structure of 1 was unquestionably confirmed by 1H, 13C, 2D-NMR, and IR spectroscopies and mass spectrometry. Its optical properties were also studied.
Authors
- Iskra Z. Koleva (ORCID: https://orcid.org/0000-0002-4080-9846)
- Lyuben Borislаvov (ORCID: https://orcid.org/0000-0002-6208-1446)
- Vesela Lozanova (ORCID: https://orcid.org/0000-0002-7748-4133)
- Rumen Lyapchev (ORCID: https://orcid.org/0000-0002-3615-2212)
- Maria Ivanova
Institutions
- Bulgarian Academy of Sciences (BG)
- Institute of General and Inorganic Chemistry (BG)
- Sofia University "St. Kliment Ohridski" (BG)
Publication Details
- Journal
- Molbank
- Published
- 2024-08-15
- DOI
- https://doi.org/10.3390/m1868
- Primary Topic
- N-Heterocyclic Carbenes in Organic and Inorganic Chemistry
- Type
- article
- Field-Weighted Citation Impact
- 0.00