Transition from Surface to Volume Expansion in Argon Clusters Coulomb Explosion

The intensity-difference spectrum technique is applied to record charge-state resolved ion energy spectra from the Coulomb explosion of small Ar clusters under well-resolved laser intensity conditions. The far-reaching control of the experimental parameters permits us to identify a striking change in the expansion pattern of the nanoplasma beyond a given intensity. The simultaneous characterization of ion charge state and energy uncovers that a reduction of the laser intensity leads to a development of low energy cuts in the ion yields, not present at higher fluence. The complex interplay of outer ionization, recombination, ion screening, and the phenomenon of ionization saturation favors a surface-driven expansion at low plasma electron temperatures. With increasing laser intensity a transition into a volume-driven Coulomb explosion is observed.