Compositional controls on the Lower Cretaceous Rodby Shale pore structure and surface area: a planned CCS top seal caprock for the Acorn storage site

• Mudstone top-seals such as silty-shales possess a wide range of grain sizes and so have complex heterogeneity of pore structure. • The combination of two fluid invasion methods allow a full range of pore body and pore throat diameter representation. • Shale mineralogy strongly influence the pore system and exposed surface area. Fine-grained lithologies above CCS reservoirs cannot automatically be assumed to be mineralogically stable, or high quality top-seals to highly pressured CO 2 as saline aquifer have previously contained hydrostatically pressured water. We have investigated the mineralogy, pore systems and surface area characteristics of the Lower Cretaceous Rodby Shale, the caprock to the Captain Sandstone at the UK's planned Acorn/Goldeneye CCS site. Rodby Shale core was logged and analysed by XRD, light microscopy, and SEM. Grain size was measured using laser particle size analysis. Mercury intrusion porosimetry and nitrogen adsorption analysis were used to characterise the pore network. The Rodby is smectite-rich and contains abundant calcite as well as quartz silt with small quantities of chlorite and plagioclase. Calcite was sourced from benthic microfossils, locally recrystallised to create a pore-filling cement. The mean pore throat and pore body diameter are about 17 nm putting the Rodby in the mesopore range and suggesting a predominance of slit-like pores. There are three lithofacies in the Rodby Shale: (i) high surface area clay-rich shale, (ii) low surface area calcite-rich shale, (iii) intermediate surface area quartz-rich. if the second lithotype encountered CO 2 , then the resulting calcite dissolution would lead to increasing surface area of the remaining shale. The Rodby Shale has good potential to be an effective barrier for CO 2 escape, based on assessments of diffusion rate and post-breakthrough advection rate as well as stability and sealing assessments.