π-Expanded [6]Helicene-Containing Nanographenes: Synthesis, Structures, and Chiroptical Properties

A family of chiral nanographenes bearing [6]helicene units has been synthesized via the classical Scholl reaction. Inserting the [6]helicene unit into the parent nanographene skeleton can result in different structural topologies and optoelectric properties. Moreover, the isolated enantiomers exhibit attractive chiroptical properties.

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Publication Details

Journal
Organic Letters
Published
2024-08-15
DOI
https://doi.org/10.1021/acs.orglett.4c02273
Citations
7
Primary Topic
Synthesis and Properties of Aromatic Compounds
Type
article
Field-Weighted Citation Impact
1.75

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article

π-Expanded [6]Helicene-Containing Nanographenes: Synthesis, Structures, and Chiroptical Properties

Jinchong Xiao, Tongtong Ye, Yi Che, Yiming Li et al.
7 citations
Organic Letters
Synthesis and Properties of Aromatic Compounds
1.75
article

π-Expanded [6]Helicene-Containing Nanographenes: Synthesis, Structures, and Chiroptical Properties

Jinchong Xiao, Tongtong Ye, Yi Che, Yiming Li, Sujuan Wang, Yanwei Shi, Bihan Leng
article en
7 citations

Abstract

A family of chiral nanographenes bearing [6]helicene units has been synthesized via the classical Scholl reaction. Inserting the [6]helicene unit into the parent nanographene skeleton can result in different structural topologies and optoelectric properties. Moreover, the isolated enantiomers exhibit attractive chiroptical properties.

Organic LettersVol. 26(34)
Hebei University (CN)
Natural Science Foundation of Hebei Province, Hubei Provincial Central Guidance Local Science and Technology Development Project
Openalex Percentile: Top 17%
Synthesis and Properties of Aromatic Compounds
1.75
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π-Expanded [6]Helicene-Containing Nanographenes: Synthesis, Structures, and Chiroptical Properties — Jinchong Xiao, Tongtong Ye, et al. · Organic Letters (2024) | TGRS Research Map | TGRS