Experimental evaluation of salt corrosion resistance of potassium salt magnesium phosphate cement coating slurry

In this work, a self-compacting potassium salt magnesium phosphate cement (PMPC) coating slurry was prepared by improving the water binder ratio and adding an appropriate amount of water glass (WG) and silica microfume (SMP). By performing long-term solution immersion tests, the following conclusions can be drawn: the remaining flexural and compressive strength values ( Δf f and Δf c ) of the PMPC specimens (M2) containing 2 % WG and 10 % SMP immersed in water, 3.5 % NaCl solution, and 5 % Na 2 SO 4 solution for 540 days were greater than 95 % and 90 %, respectively. In comparison to the reference PMPC specimen without WG and SMP (M0), the Δf f and Δf c increased by more than 30 % and 25 %, respectively. After 540 days in 3.5 % NaCl solution and 5 % Na 2 SO 4 solution, the salt corrosion coefficients ( K f and K c ) of the M2 specimen were all greater than 1. After excluding the factor of water corrosion, the salt crystals in the solution had a strengthening effect on the hardened PMPC paste. The M2 specimens experienced volume expansion after being immersed in a solution composed of water, 3.5 % NaCl solution, and 5 % Na 2 SO 4 solution for 540 days (7.21× 10 −4 , 13.52 × 10 −4 , and 10.92 × 10 −4 ); this expansion was significantly lower than that of the M0 specimen under the same conditions (13×10 −4 , 18.5×10 −4 , and 21.5×10 −4 ) due to the relatively denser initial structure. The initial water absorption rate of M2 (0.64 %–0.66 %) was significantly lower than that of M0 (0.72 %–0.75 %). After soaking in water, 3.5 % NaCl solution, and 5 % Na 2 SO 4 solution for 540 days, the water absorption of the M2 specimens increased by 64.6 %, 7.6 %, and 12.5 %, respectively, which is clearly lower than that of M0 specimens (95.9 %, 22.7 %, and 30.6 %). The increase in the water absorption of the specimen in the salt solution was also obviously smaller than that in the aqueous solution. • A self-compacting potassium salt magnesium phosphate cement (PMPC) coating slurry was prepared. • An appropriate amount of water glass (WG) and silica micro fume (SMP) was added for the improvement of the fluidity. • The strength, deformation and water absorption of PMPC slurry was tested under long-term solution immersion environment. • The effect of WG and SMP on the strength, deformation and water absorption of PMPC slurry was studied. • The corrosion resistance of PMPC slurry immersed in water, 3.5 % NaCl solution, and 5 % Na 2 SO 4 solution for 540 days was evaluated.

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Publication Details

Journal
Case Studies in Construction Materials
Published
2024-08-15
DOI
https://doi.org/10.1016/j.cscm.2024.e03633
Citations
2
Primary Topic
Magnesium Oxide Properties and Applications
Type
article
Field-Weighted Citation Impact
0.23

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article

Experimental evaluation of salt corrosion resistance of potassium salt magnesium phosphate cement coating slurry

Yin Lv, Peng Jiang, Jianming Yang, Xiaohui Xu et al.
2 citations
Case Studies in Construction Materials
Magnesium Oxide Properties and Applications
0.23
article

Experimental evaluation of salt corrosion resistance of potassium salt magnesium phosphate cement coating slurry

Yin Lv, Peng Jiang, Jianming Yang, Xiaohui Xu, Yubing Du
article en
2 citations

Abstract

In this work, a self-compacting potassium salt magnesium phosphate cement (PMPC) coating slurry was prepared by improving the water binder ratio and adding an appropriate amount of water glass (WG) and silica microfume (SMP). By performing long-term solution immersion tests, the following conclusions can be drawn: the remaining flexural and compressive strength values ( Δf f and Δf c ) of the PMPC specimens (M2) containing 2 % WG and 10 % SMP immersed in water, 3.5 % NaCl solution, and 5 % Na 2 SO 4 solution for 540 days were greater than 95 % and 90 %, respectively. In comparison to the reference PMPC specimen without WG and SMP (M0), the Δf f and Δf c increased by more than 30 % and 25 %, respectively. After 540 days in 3.5 % NaCl solution and 5 % Na 2 SO 4 solution, the salt corrosion coefficients ( K f and K c ) of the M2 specimen were all greater than 1. After excluding the factor of water corrosion, the salt crystals in the solution had a strengthening effect on the hardened PMPC paste. The M2 specimens experienced volume expansion after being immersed in a solution composed of water, 3.5 % NaCl solution, and 5 % Na 2 SO 4 solution for 540 days (7.21× 10 −4 , 13.52 × 10 −4 , and 10.92 × 10 −4 ); this expansion was significantly lower than that of the M0 specimen under the same conditions (13×10 −4 , 18.5×10 −4 , and 21.5×10 −4 ) due to the relatively denser initial structure. The initial water absorption rate of M2 (0.64 %–0.66 %) was significantly lower than that of M0 (0.72 %–0.75 %). After soaking in water, 3.5 % NaCl solution, and 5 % Na 2 SO 4 solution for 540 days, the water absorption of the M2 specimens increased by 64.6 %, 7.6 %, and 12.5 %, respectively, which is clearly lower than that of M0 specimens (95.9 %, 22.7 %, and 30.6 %). The increase in the water absorption of the specimen in the salt solution was also obviously smaller than that in the aqueous solution. • A self-compacting potassium salt magnesium phosphate cement (PMPC) coating slurry was prepared. • An appropriate amount of water glass (WG) and silica micro fume (SMP) was added for the improvement of the fluidity. • The strength, deformation and water absorption of PMPC slurry was tested under long-term solution immersion environment. • The effect of WG and SMP on the strength, deformation and water absorption of PMPC slurry was studied. • The corrosion resistance of PMPC slurry immersed in water, 3.5 % NaCl solution, and 5 % Na 2 SO 4 solution for 540 days was evaluated.

Case Studies in Construction MaterialsVol. 21
Nantong University (CN), Yancheng Institute of Technology (CN), China Construction Eighth Engineering Division (China) (CN)
National Aerospace Science Foundation of China, Joint Project of Industry-University-Research of Jiangsu Province
Openalex Percentile: Top 52%
Magnesium Oxide Properties and Applications
0.23
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