CIELAB Color Space as a Field for Tracking Color-Changing Chemical Reactions of Polymeric pH Indicators

Two types of cross-linked polymeric dye films that exhibit reversible color changes in response to pH were prepared. Upon protonation, films with a nitrophenol dye moiety (NP) changed from yellow to colorless, whereas films with an azobenzene dye moiety (AB) changed from yellow to reddish-purple. The colored light transmitted through these films from a D65 white-light source was measured colorimetrically, and the transition of the chromaticity point in CIELAB upon protonation of the polymeric dyes was observed. At low dye concentrations ([NP] < 4.7 × 10^-5 and [AB] < 2.7 × 10^-5 mol L^-1), linear loci of the chromaticity points were displayed for both polymeric dye films, indicating perceptual linearity. This linearity is caused by the avoidance of nonlinear perceptual phenomena such as the Abney effect and the Bezold-Brücke phenomenon. The perceptual linearity of space is a necessary condition for achieving stoichiometric linearity, which requires an additional linear relationship between the dye concentration and each component, <i>a</i>*, <i>b</i>*, and <i>L</i>*. A geometric equation that included the AB concentration and the protonation ratio of AB was used to successfully depict, on the basis of stoichiometric linearity, the protonation of the polymeric AB films three-dimensionally in the restricted area of CIELAB.