Properties of Hydrolyzed Polyalumotris(acetylacetonato)ethylsiloxane

The work is devoted to the study of the structural and sorption properties of metal exchangers obtained under conditions of extraction by hydrochloric acid (1:2) of the product of interaction of tris(3-chlorosulfenyl)-2,4-aluminum pentanedionate with vinyl trichlorosilane. The reaction was considered using two organic solvents – chloroform and toluene. A comparison of diffractometric parameters, elemental analysis, NMR spectra, thermogravimetric curves, as well as surfaces (SEM) and internal structure of isolated substances was presented. The capacity of the products with respect to Fe³⁺ is on the order of 7.1 mg·eq/g.

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Publication Details

Journal
Журнал Общей Химии
Published
2024-08-13
DOI
https://doi.org/10.31857/s0044460x24030146
Primary Topic
Chemical Synthesis and Characterization
Type
article
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article

Properties of Hydrolyzed Polyalumotris(acetylacetonato)ethylsiloxane

Н. П. Шапкин, A. N. Fedorets, А. О. Лембиков, А. Н. Драньков et al.
Журнал Общей Химии
Chemical Synthesis and Characterization
article

Properties of Hydrolyzed Polyalumotris(acetylacetonato)ethylsiloxane

Н. П. Шапкин, A. N. Fedorets, А. О. Лембиков, А. Н. Драньков, K. A. Pervakov, V. G. Savchenko
article en

Abstract

The work is devoted to the study of the structural and sorption properties of metal exchangers obtained under conditions of extraction by hydrochloric acid (1:2) of the product of interaction of tris(3-chlorosulfenyl)-2,4-aluminum pentanedionate with vinyl trichlorosilane. The reaction was considered using two organic solvents – chloroform and toluene. A comparison of diffractometric parameters, elemental analysis, NMR spectra, thermogravimetric curves, as well as surfaces (SEM) and internal structure of isolated substances was presented. The capacity of the products with respect to Fe³⁺ is on the order of 7.1 mg·eq/g.

Журнал Общей ХимииVol. 94(3)
Far Eastern Federal University (RU)
Clean water and sanitation
Openalex Percentile: Top 85%
Chemical Synthesis and Characterization
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