Heating Rate Sensitive Polyethylene Terephthalate

Smart materials react to external triggers by changing size, color, mechanical properties, or permeability. The next generation of smart materials will be able to not only recognize and react to external triggers but also to their dynamics. The only existing example of such a material is heating rate-sensitive polymorphous cross-linked syndiotactic polypropylene. This study presents a new principle of a heating rate-sensitive material on the example of cross-linked and fully amorphous quenchable semi-crystalline polyethylene terephthalate (x-PET). The x-PET is stretched to high elongation above its melting temperature and constrained quenched to a fully amorphous state. Then the polymer is heated to 120-170 °C with different heating rates. Due to its heating-rate sensitivity, x-PET shrinks to different stabilized lengths dependent on the heating rate. The new length can be used to read out the heating rate and to specifically answer to this by mechanically switching a process. Detailed analytics of this process reveal that amorphous stretched x-PET is starting the retraction above T_g and simultaneously stopping it by crystallization. The different rates of these processes result in the heating rate sensitivity of x-PET.