MODELLING OF HYDROGEN FLOW FROM GAS MIXTURES THROUGH NICKEL CAPILLARIES CONSIDERING THE NONUNIFORMITY OF TEMPERATURE DISTRIBUTION

A mathematical model of the flow of hydrogen from gas mixtures through the walls of capillary tubes made of metallic nickel has been developed, taking into account the inhomogeneity of the partial pressure of hydrogen along a long tube, as well as temperature nonuniformity in different regions of the tube. Using the model and relying on experimental data, the kinetic parameters of hydrogen transport were calculated within the temperature range of 600-850 °С and the hydrogen partial pressure range of 0.3-0.8 atm. The model can be used in the design of membrane modules for hydrogen separation from gas mixtures to calculate the length of individual membranes, their number, and the optimal flow rate of the hydrogen-containing gas mixture through the membrane.