First‐Principles Calculation and In Situ Observation on the Precipitation of Inclusions during Solidification of a High Sulfur Steel
The precipitation process of inclusions in the high sulfur steel with the cerium addition is observed using the high‐temperature confocal scanning laser microscope (CSLM). Rare earth (Re) inclusions formed in the molten steel, and MnS inclusions precipitate along grain boundaries or on oxide cores at the end of solidification. With the addition of cerium, the average aspect ratio of inclusions in the steel decreases from 6.5 to 5.0, and the addition of cerium effectively modifies the elongated MnS. Thermodynamic calculations show the inclusion transformation during solidification, yet it lacked the formation of Ce 2 O 2 S and Re sulfides. According to the first‐principles calculation, the priority of the inclusion formation was Ce 2 O 3 > CeAlO 3 , Ce 2 O 2 S > CeS > Ce 3 S 4 > MnS. The stability of MnS inclusions is much lower than that of cerium‐containing inclusions. It is in situ observed that the addition of cerium promotes the formation of cerium‐containing inclusions and reduces the precipitation of MnS in the high sulfur steel.
Authors
- Ying Ren (ORCID: https://orcid.org/0000-0003-4567-7085)
- Jinshu Wang (ORCID: https://orcid.org/0000-0002-7970-665X)
- Lifeng Zhang (ORCID: https://orcid.org/0000-0001-7394-5433)
- Haixin Yang
Institutions
- North China University of Technology (CN)
- Beijing University of Technology (CN)
- University of Science and Technology Beijing (CN)
Publication Details
- Journal
- steel research international
- Published
- 2024-08-12
- DOI
- https://doi.org/10.1002/srin.202400465
- Citations
- 4
- Primary Topic
- Metallurgical Processes and Thermodynamics
- Type
- article
- Field-Weighted Citation Impact
- 0.85
Funders
- National Natural Science Foundation of China
- University of Science and Technology Beijing
- North China University of Technology
- Key Technologies Research and Development Program