Investigation of polymeric organofluorosilicates and organofluorogermanates
The reactions of representative organochlorosilanes and organochlorogermanes with alkali metal fluorides (LiF, NaF, KF, RbF, CsF) were investigated by NMR spectroscopy and showed not only the fluorination to organofluorosilanes or organofluorogermanes but also the formation of organofluorosilicates and organofluorogermanates. The synthesis and crystal structures of two new polymeric organofluorogermanates, [K][Ph2GeF3]∙0.75 MeCN and [Cs][Ph2GeF3]∙THF, are presented.
Authors
- Jan Gnidovec (ORCID: https://orcid.org/0000-0003-4318-595X)
- Gašper Tavčar (ORCID: https://orcid.org/0000-0001-9891-6153)
Institutions
- Jožef Stefan Institute (SI)
- Jožef Stefan International Postgraduate School (SI)
Publication Details
- Journal
- Journal of Fluorine Chemistry
- Published
- 2024-08-01
- DOI
- https://doi.org/10.1016/j.jfluchem.2024.110332
- Primary Topic
- Fluorine in Organic Chemistry
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- Grantová Agentura České Republiky
- Javna Agencija za Raziskovalno Dejavnost RS