Synthesis of Three‐Dimensional Chiral Covalent Organic Frameworks Using Surfactant as Inducer in Water

Comprehensive Summary Chiral covalent organic frameworks (COFs) have shown promising applications in asymmetric catalysis, enantiomer separation and chiral recognition due to their tunable structures and permanent porosity. Currently, synthesis of chiral COFs mainly relies on direct‐ synthesis method which requires asymmetric monomers to polymerize and crystallize with symmetric monomers and post‐synthesis method which has been greatly limited to having complete reactions with the micro‐/meso‐sized pores of COFs. Recently, the synthesis of two‐dimensional COFs by covalent replacement of chiral competitor has been reported. Herein, we present the synthesis of three types of 3D COFs with tunable chirality using chiral amino acid derivative surfactant as inducer in water under ambient conditions. The hydrogen bonds and electrostatic interactions between amino acid derivative surfactant and monomers as well as their precursors facilitate the transfer of the chirality.

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Publication Details

Journal
Chinese Journal of Chemistry
Published
2024-08-08
DOI
https://doi.org/10.1002/cjoc.202400552
Citations
2
Primary Topic
Covalent Organic Framework Applications
Type
article
Field-Weighted Citation Impact
0.23

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article

Synthesis of Three‐Dimensional Chiral Covalent Organic Frameworks Using Surfactant as Inducer in Water

Wei Liu, Xiaoshu Wei, Xin Dong, Yonghang Yang et al.
2 citations
Chinese Journal of Chemistry
Covalent Organic Framework Applications
0.23
article

Synthesis of Three‐Dimensional Chiral Covalent Organic Frameworks Using Surfactant as Inducer in Water

Wei Liu, Xiaoshu Wei, Xin Dong, Yonghang Yang, Zhipeng Zhou, Jiaxing Lu, Yuyao Li, Yuexian Hong, Zhikun Zheng, Weiqi Cheng, Zhongke Yuan, Xudong Chen, Changye Zhan, Meiying Huang
article en
2 citations

Abstract

Comprehensive Summary Chiral covalent organic frameworks (COFs) have shown promising applications in asymmetric catalysis, enantiomer separation and chiral recognition due to their tunable structures and permanent porosity. Currently, synthesis of chiral COFs mainly relies on direct‐ synthesis method which requires asymmetric monomers to polymerize and crystallize with symmetric monomers and post‐synthesis method which has been greatly limited to having complete reactions with the micro‐/meso‐sized pores of COFs. Recently, the synthesis of two‐dimensional COFs by covalent replacement of chiral competitor has been reported. Herein, we present the synthesis of three types of 3D COFs with tunable chirality using chiral amino acid derivative surfactant as inducer in water under ambient conditions. The hydrogen bonds and electrostatic interactions between amino acid derivative surfactant and monomers as well as their precursors facilitate the transfer of the chirality.

Chinese Journal of ChemistryVol. 42(23)
Guangdong University of Technology (CN), Sun Yat-sen University (CN), Peking University (CN), Ji Hua Laboratory (CN), Sun Yat-sen Memorial Hospital (CN), Beijing National Laboratory for Molecular Sciences (CN), State Key Laboratory of Optoelectronic Materials and Technology
National Natural Science Foundation of China, Fundamental Research Funds for the Central Universities
Clean water and sanitation
Openalex Percentile: Top 52%
Covalent Organic Framework Applications
0.23
DOISourceOpenAlex
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