Influence of Long-Term Moisture Exposure and Temperature on the Mechanical Properties of Hybrid FRP Composite Specimens

The present experimental study assesses the mechanical properties of glass/carbon/glass hybrid composite laminates after being exposed to moisture in a deep freezer and elevated temperatures for extended periods. The top and bottom layers of the hybrid laminates are reinforced with glass fibre, and the middle layer is reinforced with carbon fibre using the epoxy matrix as a binder polymer material. The hybrid laminates were manufactured using the resin transfer moulding method, and their compressive and tensile properties were determined using a tensile testing machine. The storage modulus, loss modulus, and damping factors of all groups of laminates were identified using a dynamic mechanical analysis as a function of temperature and vibration frequency. The experimental results on compressive and tensile properties revealed slight variations when the hybrid laminates were kept at low temperatures in a deep freezer for extended periods. This might occur due to the increasing molecular crosslinking of the polymer network. As the testing temperature increased, compressive, tensile, storage modules, loss modulus, and damping factors decreased. This might occur due to the increasing mobility of the binder material. Particularly, the highest stiffness parameters were obtained at −80 °C/GCG (glass/carbon/glass) laminates due to the presence of a beta transition in the glassy region. The relationships between the glass transitions and the targeted frequencies were characterized. The values of the glass transition shift towards higher temperatures as the frequency increases. This might occur due to a reduction in the gaps between the crosslinking of the epoxy network when the frequency increases. The accuracy of the storage modulus results was compared with the empirical models. The model based on the Arrhenius law provided the closest correlation. Meanwhile, another model was observed that was not accurate enough to predict when gamma and beta relaxations occur in a glassy state.