Complexity Scaling of Liquid Dynamics

According to excess-entropy scaling, dynamic properties of liquids like viscosity and diffusion coefficient are determined by the entropy. This link between dynamics and thermodynamics is increasingly studied and of interest also for industrial applications, but hampered by the challenge of calculating entropy efficiently. Utilizing the fact that entropy is basically the Kolmogorov complexity, which can be estimated from optimal compression algorithms [Avinery et al., Phys. Rev. Lett. 123, 178102 (2019)PRLTAO0031-900710.1103/PhysRevLett.123.178102; Martiniani et al., Phys. Rev. X 9, 011031 (2019)PRXHAE2160-330810.1103/PhysRevX.9.011031], we here demonstrate that the diffusion coefficients of four simple liquids follow a quasiuniversal exponential function of the optimal compression length of a single equilibrium configuration. We conclude that "complexity scaling" has the potential to become a useful tool for estimating dynamic properties of any liquid from a single configuration.

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Publication Details

Journal
Physical Review Letters
Published
2024-08-09
DOI
https://doi.org/10.1103/physrevlett.133.068001
Citations
4
Primary Topic
Material Dynamics and Properties
Type
article
Field-Weighted Citation Impact
0.47

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article

Complexity Scaling of Liquid Dynamics

Lorenzo Costigliola, Ian Douglass, Jeppe C. Dyre
4 citations
Physical Review Letters
Material Dynamics and Properties
0.47
article

Complexity Scaling of Liquid Dynamics

Lorenzo Costigliola, Ian Douglass, Jeppe C. Dyre
article en
4 citations

Abstract

According to excess-entropy scaling, dynamic properties of liquids like viscosity and diffusion coefficient are determined by the entropy. This link between dynamics and thermodynamics is increasingly studied and of interest also for industrial applications, but hampered by the challenge of calculating entropy efficiently. Utilizing the fact that entropy is basically the Kolmogorov complexity, which can be estimated from optimal compression algorithms [Avinery et al., Phys. Rev. Lett. 123, 178102 (2019)PRLTAO0031-900710.1103/PhysRevLett.123.178102; Martiniani et al., Phys. Rev. X 9, 011031 (2019)PRXHAE2160-330810.1103/PhysRevX.9.011031], we here demonstrate that the diffusion coefficients of four simple liquids follow a quasiuniversal exponential function of the optimal compression length of a single equilibrium configuration. We conclude that "complexity scaling" has the potential to become a useful tool for estimating dynamic properties of any liquid from a single configuration.

Physical Review LettersVol. 133(6)
Roskilde University (DK)
Villum Fonden
Openalex Percentile: Top 39%
Material Dynamics and Properties
0.47
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Complexity Scaling of Liquid Dynamics — Lorenzo Costigliola, Ian Douglass, et al. · Physical Review Letters (2024) | TGRS Research Map | TGRS