Recent Advances in the Chemistry and Application of SF5-Compounds
Abstract This review article outlines the literature from 2022 to 2024 covering developments in SF5 chemistry. Recent synthetic methodologies of SF5-containing building blocks are reported. These methods include the synthesis of SF5Cl and its use in pentafluorosulfanylation reactions and oxidative fluorination reactions. Moreover, the reactivity of SF5-alkynes as versatile platform to access new SF5-compounds is described. Finally, the effects of the SF5 moiety are highlighted according to its application in different fields, such as biological/medicinal chemistry, catalysis, and material sciences. 1 Introduction 2 Access to SF5-Containing Building Blocks 2.1 By Means of SF5Cl 2.1.1 Generation of SF5Cl 2.2 By Means of Oxidative Fluorination 2.3 By Means of SF5-Alkynes 2.4 Other Miscellaneous Aromatic and Aliphatic SF5-Compounds 3 Applications 3.1 Medicinal and Biological Chemistry 3.2 Material Science 3.3 Catalysis 4 Conclusion
Authors
- Mariam Abd El Sater (ORCID: https://orcid.org/0009-0000-1148-1581)
- Nicolas Blanchard (ORCID: https://orcid.org/0000-0002-3097-0548)
- Vincent Bizet (ORCID: https://orcid.org/0000-0002-0870-1747)
- Lucas Popek (ORCID: https://orcid.org/0000-0002-8894-1467)
Institutions
- Centre National de la Recherche Scientifique (FR)
- Université de Haute-Alsace (FR)
- Institut de Chimie de Strasbourg (FR)
- Laboratoire de Chimie Moléculaire (FR)
- Université de Strasbourg (FR)
Publication Details
- Journal
- Synthesis
- Published
- 2024-08-09
- DOI
- https://doi.org/10.1055/a-2383-6620
- Citations
- 21
- Primary Topic
- Inorganic Fluorides and Related Compounds
- Type
- article
- Field-Weighted Citation Impact
- 3.33
Funders
- Université de Strasbourg
- Centre National de la Recherche Scientifique