Synthesis, crystal structure and Hirshfeld surface analysis of 1-[(1-octyl-1<i>H</i>-1,2,3-triazol-4-yl)methyl]-3-phenyl-1,2-dihydroquinoxalin-2(1<i>H</i>)-one
In the title mol-ecule, C<sub>25</sub>H<sub>29</sub>N<sub>5</sub>O, the di-hydro-quinoxaline unit is not quite planar (r.m.s. deviation = 0.030 Å) as there is a dihedral angle of 2.69 (3)° between the mean planes of the constituent rings and the mol-ecule adopts a hairpin conformation. In the crystal, the polar portions of the mol-ecules are associated through C-H⋯O and C-H⋯N hydrogen bonds and C-H⋯π(ring) and C=O⋯π(ring) inter-actions, forming thick layers parallel to the <i>bc</i> plane and with the <i>n</i>-octyl groups on the outside surfaces.
Authors
- Youssef Ramli (ORCID: https://orcid.org/0000-0002-6885-5692)
- Nadeem Abad (ORCID: https://orcid.org/0009-0003-9288-4789)
- Camille Kalonji Mubengayi
- Joel T. Mague (ORCID: https://orcid.org/0000-0003-3488-1945)
- Abdulsalam Alsubari
- El Mokhtar Essassi
Institutions
- Tulane University (US)
- Mohammed V University (MA)
- Institut Supérieur de Technique Médicale (CD)
Publication Details
- Journal
- Acta Crystallographica Section E Crystallographic Communications
- Published
- 2024-08-09
- DOI
- https://doi.org/10.1107/s2056989024007746
- Primary Topic
- Synthesis and Biological Evaluation
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- National Science Foundation
- Tulane University