Crystal structure of bis(β-alaninium) tetrabromidoplumbate

The title compound, poly[bis-(β-alaninium) [[di-bromido-plumbate]-di-μ-di-bromido]] {(C<sub>2</sub>H<sub>8</sub>NO<sub>2</sub>)<sub>2</sub>[PbBr<sub>4</sub>]} <sub><i>n</i></sub> or (<i>β</i>-AlaH)<sub>2</sub>PbBr<sub>4</sub>, crystallizes in the monoclinic space group <i>P</i>2<sub>1</sub>/<i>n</i>. The (PbBr<sub>4</sub>)<sup>2-</sup> anion is located on a general position and has a two-dimensional polymeric structure. The Pb center is holodirected. The supra-molecular network is mainly based on O-H⋯Br, N-H⋯Br and N-H⋯O hydrogen bonds.

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Publication Details

Journal
Acta Crystallographica Section E Crystallographic Communications
Published
2024-08-09
DOI
https://doi.org/10.1107/s2056989024007722
Citations
2
Primary Topic
Crystal structures of chemical compounds
Type
article
Field-Weighted Citation Impact
0.32
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article

Crystal structure of bis(β-alaninium) tetrabromidoplumbate

Ruben Yu. Chilingaryan, G.S. Tonoyan, A.A. Margaryan, A.M. Petrosyan et al.
2 citations
Acta Crystallographica Section E Crystallographic Communications
Crystal structures of chemical compounds
0.32
article

Crystal structure of bis(β-alaninium) tetrabromidoplumbate

Ruben Yu. Chilingaryan, G.S. Tonoyan, A.A. Margaryan, A.M. Petrosyan, A.H. Mkrtchyan, Gerald Giester, V.V. Ghazaryan
article en
2 citations

Abstract

The title compound, poly[bis-(β-alaninium) [[di-bromido-plumbate]-di-μ-di-bromido]] {(C<sub>2</sub>H<sub>8</sub>NO<sub>2</sub>)<sub>2</sub>[PbBr<sub>4</sub>]} <sub><i>n</i></sub> or (<i>β</i>-AlaH)<sub>2</sub>PbBr<sub>4</sub>, crystallizes in the monoclinic space group <i>P</i>2<sub>1</sub>/<i>n</i>. The (PbBr<sub>4</sub>)<sup>2-</sup> anion is located on a general position and has a two-dimensional polymeric structure. The Pb center is holodirected. The supra-molecular network is mainly based on O-H⋯Br, N-H⋯Br and N-H⋯O hydrogen bonds.

Acta Crystallographica Section E Crystallographic CommunicationsVol. 80(9)
University of Vienna (AT), Institute for Informatics and Automation Problems (AM)
Openalex Percentile: Top 50%
Crystal structures of chemical compounds
0.32
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