Enhanced thermoregulation performance of knitted fabrics using phase change material incorporated thermoplastic polyurethane and cellulose acetate nanofibers

Abstract Nanofibers act as carriers in systems containing functional materials produced via electrospinning method. By this way, it is possible to transport functional materials with polymer nanofibers, besides having a large surface area compared to their volume, the encapsulation process, which includes complex preparation processes, is eliminated here, and functional materials such as phase‐change materials (PCMs) can be conveniently integrated directly into the carrier material by electrospinning method. The resulting nanofiber membrane can also be used in combination with textile fabrics. This study aims to develop PCM containing nanofibrous membrane coated knitted fabric structures with heat regulation capabilities. Two types of PCMs, hexadecane and octadecane loaded into thermoplastic polyurethane (TPU) and cellulose acetate (CA) nanofibers, directly electrospun on cotton (CO), cotton/polyester (CO/PES), cotton/acrylic (CO/PAC) knitted fabrics for thermoregulation. These nanofiber‐coated fabrics were characterized by scanning electron microscopy (SEM) and differential scanning colorimetry (DSC), and their comfort properties were evaluated by water vapor and air permeability tests and compared with a commercial microcapsule impregnated fabric. According to DSC results, PCM incorporated CA nanofibers had better heat storage capacity than TPU nanofibers and microcapsule applied fabrics. Although PCM‐loaded CA nanofibers may not block airflow as effectively as TPU nanofibers, when a proper coating is achieved air permeability can be decreased to 21.70 L/m 2 /s, along with a heat storage capacity of 26.38 J/g and still having permeability to water vapor (%40). Highlights Phase change materials were integrated directly to the carrier material by electrospinning PCM integrated nanofiber coating reduced air permeability PCM integrated nanofiber coating did not block water vapor permeability Electrspun cellulose acetate +PCM coating had better heat storage capacity