Long-term dissolved organic carbon changes in Woronora drinking water system in Australia

Assessing historical records of DOC concentrations (DOC) in drinking water sources is important for water utilities to understand long-term planning for infrastructure needs. This study investigates 15-20 years of historical data of the Woronora water supply catchment in Australia inclusive of the water filtration plant (WFP), the lake from where the water was drawn for WFP supply, and the two primary river inputs. The DOC at each site ranged from 0.8 mg L^-1 to 13.9 mg L^-1, with the highest and lowest concentrations observed in Waratah Rivulet. The DOC in the lake and WFP significantly (p < 0.001) increased at annual change rates of 0.192 and 0.180 mg L^-1 yr^-1. However, Woronora River showed a ∼50% lower rate of DOC increase at 0.096 mg L^-1 yr^-1 (p < 0.001), while Waratah Rivulet showed no trend (p > 0.05). UV₂₅₄ also showed increasing trends at Woronora River, Lake Woronora, and Woronora WFP, indicating an increase in aromatic DOC compounds in all three sites. Waratah Rivulet, however, transported more than 60% of the total DOC load into Lake Woronora due to high flow volumes (more than 65% of total annual system flow). Annual DOC load to the lake is positively correlated with annual rainfall (R² > 0.92; p < 0.001). The higher percentage (>73%) of the samples had SUVA₂₅₄ greater than 2 L mg ^-1 m^-1 in all four sites indicating a dominance of hydrophobic DOC. The terrestrial plant-derived DOC has increased in Lake Woronora, predominantly influenced by historical rainfall magnitude. The results underscore the importance of considering the impact of increased DOC at the treatment plant intake for the planning and operation of the Woronora water supply system.